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UNK30.TXT
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1993-02-13
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202 lines
Insoluble in the normal reagents.
1348
The unknown is not acidic nor basic.
Peak near 9ppm is exchangeable. Solvent is deuterochloroform.
ßßßααßΓΓΓΓßßßßßßßßßßαααßßßßßßßßßßααα▀▀αΓΓΓßαααααßααααßα▀▐▐▐▐▀▀▀α▌▌╪╙╥╤╙╫╓╤╩╟╛│╟─╟╬═╘╤╠╟╝┬╠╥╤╥╘╨╠╔┼┴├╟╙╥╓┘╪╓╒╓╪┌▄▌▌▄██▄▌▌▐▀▀▀▐▐▀▀▀ααααααααααßαααßßßßßßßßßßßßßαßßßßΓΓαßßßßßßαßα▀▀ßßΓααßααααααΓßΓΓΓΓßßΓΓαααßßαßßßßßßΓßßßßßßΓßßαΣΦΓΓßßßßΓßßßαα▀αßßßßßßΓßßßΓßßßααααα
▀▀▀ααßαßßßΓΓΓΓΓßßα▀▀ααααßΓßßßαααααααßßßßßßΓΓßßßßßßßßßßßΓΓΓßßΓßßßααßßßßßßßα▀▀αßααßßα▀▐αßßßßßßßßα▐┘╓╧╚╛çyöó─▌▌▐▐▐▀▀αßßßααα▀▀▀αααααßßα▀▌▐αßßαΓΓΓßßαßßßαßßΓßßßΓßßßßßαßßαα▀▌▌▌▀αßßΓΓΓΓΓßßΓΓΓα▐▌█╪╤╟n! ]az¥╜█▄▌▐▀▀▀▀▀▀▐▀▀▀αααααααααα▀ßα▀▀▀αßαααααααß▀▀αααααααα▀▀ααß
ßαααααααα▀▀▀▀αα▀▀ααßßßßßßßßßßΓßßßßßααßßßßßßßßßßααßßΓΓΓßßßßααΓßαßßßßΓΓßßßßßßßßΓßßΓΓΓΓßßßßΓΓßßßßΓßß▀╫╦═╦╫▀αßßßßßßΓΓΓΓΓNÿ!>└%ûu"┤ #
ππΓΓΓΓΓΓΓΓΓΓΓΓΓΓΓΓΓΓΓΓΓΓΓΓΓΓΓΓΓΓΓΓΓΓΓΓΓΓΓΓΓΓΓΓΓΓΓΓΓΓΓΓΓΓΓΓΓΓΓΓπππΓΓΓΓΓΓΓΓΓΓΓΓΓπΓßßßΓΓΓΓΓΓΓΓΓΓΓΓßΓΓßßßßΓΓαßΓΓαααααααααßααααααααααα▀▐▐▐▐▐▌▌▌▌┌███┘┘┌┌┌██▄▌▌▌▐▀▀▀▀αααααα▀ααßαααααααßßααL
#
Assignments may be 5 Ar (Ph ?), isolated methylene and methyl, 1 exchangeable.
#
dummy ms
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Only nitrogen was found.
264048
Halogens and sulfur are not present in this compound.
No residue was left after burning with a smoky flame.
#
The compound is probably aromatic and completely organic.
83-85 degrees.
#
A low melting solid.
Nujol mull
%&%%&%%%$%%%%%%%%%%%&&&&&&''''()))))***++,,,----../01000012469=GYcéùÆïÄûïyjcld\TZcc\S[ffcb]Z[dnä»─╓╓ßΦ╫╩╕│┴╦┴}S@9530..../0.......---,,,+***)))(''''''&'''&&&&&&&'&&&&&&&&&&&&&&&&&&%%%%%%%%%%%%%%%%%%%%%&'(&%$$$$$$%%%&'&%%%%%&%%&&&'((()))*++,./4=Rmëó¬│╣ÜàtrÇ
ö░╘▐ªéob`[`kâÖ¡qXCP^|ú½¿£è|h\RPaüâfaec|àÆææÑ└╝▒úÉztéèjZWastozçumsézkktwlcSDAECA>;=CO?51...02;Eb|¢ocNA:731/...----0473-,++++-0561//3401..2750,*)(()),?D/+*((-382-+)))'(**)('()+.4V}ôérbQNRVWZ]YZâÉd72.+(''1<,(&'""""!""&++1)%#&,PI,4WM)%#"$&%"!! $$(+-.
#
The compound is a mono-substituted amide with a monosubstituted benzene ring.
Too high - decomposition occurred.
#
Typical behaviour for a solid.
Optically inactive.
#
The molecule is not chiral.
Not usually measured for a solid.
#
Best to make this measurement on a liquid.
Not usually measured for a solid.
#
Measure this for a liquid.
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dummy cmr
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No precipitate was formed.
2227282950
The unknown is not an aldehyde or ketone.
No positive result.
3344454651
The unknown is not an alcohol, phenol or acid.
No positive result was obtained.
#
This compound is not a primary or secondary amine.
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No reaction could be seen.
14
The unknown is not an ester.
No apparent reaction took place.
#
Nitro groups are absent from the compound.
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No positive result.
3344454651
The compound is not an alcohol, phenol or a primary or secondary amine.
A red colour formed.
#
This result shows that the compound is an amide or cyanide (nitrile).
No reaction was noticed.
#
The compound is not unsaturated nor is it easily oxidised.
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No colour change was observed.
232850
The compound is not a sugar.
No observable change.
#
No nitro groups are present.
No reaction was seen.
#
The unknown is not a phenol nor is it unsaturated.
No positive result.
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The compound is not an ether.
No change in colour was noticed.
#
The unknown is not a phenol.
No reaction was observed.
#
The compound is not a primary amine.
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No reaction.
#
This result indicates that the compound is not a primary or secondary amine.
No apparent change could be seen.
#
The unknown is not an amino acid.
No positive result.
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No foul smell equals no primary amine.
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A vigorous reaction giving a solution took place.
#
Typical of N- and/or O-containing compounds.
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No change could be seen.
#
The unknown is not a primary amine.
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No reaction occurred.
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The compound is not unsaturated. It is also not a phenol.
The compound reacted with aqueous base to give an insoluble liquid product.
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The hydrolysis product is a water insoluble, nonvolatile liquid:- eg an amine.
No positive result.
3344454651
The unknown is not an alcohol, phenol or amine (prim. or sec.).
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colourless solid
010507
3153
81
Decarboxylation occurred forming another acid with amide m.p. 79-82 degrees.
2
ù│½─»⌐cÑ╞^Æ│¿¬╡╖
ñ¥╢╕Ñ╢y¼ƒPq╣┤░│╟qª╖[í⌐╡»
solid amide
3
acetoacetanilide
ethylphenylacetanilide
4-n-propylacetanilide